How to use simple-pip with other desktop apps
You can use this extension with most other apps built using Electron, since they allow you to execute code with the console.
Here's a tutorial I made if you're interested:
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Open a stream or video on any Electron app.
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Copy the extension's main script to your clipboard.
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Open the developer tools on Twitch by pressing Ctrl+Shift+I (Windows) or ⌘+⌥+I (macOS).
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Press Console in the top bar.
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Paste the code and press enter to execute it.
It's a hacky method, but at least it works until other apps come up with their own official methods.